CobaltMaghrebV1, France, Analysis, bibRecord, 000332

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

Identifieur interne : 000332 ( France/Analysis ); précédent : 000331; suivant : 000333

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

Auteurs : J. Derouet [France] ; L. Beaury [France] ; P. Porcher [France] ; R. Olazcuaga [France] ; J. M. Dance [France] ; G. Le Flem [France] ; A. El Bouari [Maroc] ; A. El Jazouli [Maroc]

Source :

Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.

RBID : ISTEX:BD8CE3E5836376F805B024A2E41B8B6493B2AEBE

Descripteurs français

Pascal (Inist)
- 7170C, 7530C, Champ cristallin, Co O P Ti, Co0,5Ti2(PO4)3, Cobalt phosphate, Composé quaternaire, Etude théorique, Facteur g, Modèle phénoménologique, Méthode semiempirique, Niveau énergie, Polycristal, Susceptibilité magnétique, Titane phosphate.

English descriptors

KwdEn :
- Cobalt phosphates, Crystal field, Energy levels, Magnetic susceptibility, Phenomenological model, Polycrystals, Quaternary compounds, Semiempirical method, Theoretical study, Titanium phosphates, g-factor.

Abstract

The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature andgvalues) of the polycrystalline Co0.5Ti2(PO4)3were simultaneously reproduced by use of a crystal field theory involving a set ofFk,ζ, free ion, andBkqcrystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assignR32 as the space group of the crystal structure.

Url:

https://api.istex.fr/document/BD8CE3E5836376F805B024A2E41B8B6493B2AEBE/fulltext/pdf

DOI: 10.1006/jssc.1998.8098

Affiliations:

France, Maroc
Aquitaine, Nouvelle-Aquitaine, Île-de-France
Paris, Pessac

Links to Exploration step

ISTEX:BD8CE3E5836376F805B024A2E41B8B6493B2AEBE

Le document en format XML

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A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

Source :

Descripteurs français

English descriptors

Abstract

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Links to Exploration step

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